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common & basic formulas for mineral processing calculations

common & basic formulas for mineral processing calculations

The control of a milling operation is a problem in imponderables: from the moment that the ore drops into the mill scoop the process becomes continuous, and continuity ceases only when the products finally come to rest at the concentrate bins and on the tailing dams. Material in process often cannot be weighed without a disturbance of continuity; consequently, mill control must depend upon the sampling of material in flux. From these samples the essential information is derived by means of analyses for metal content, particle size distribution, and content of water or other ingredient in the ore pulp.

The following formulas were developed during a long association not only with design and construction, but also with the operation of ore dressing plants. These formulas are herein the hope that they would prove of value to others in the ore dressing industry.

Pulp densities indicate by means of a tabulation the percentages of solids (or liquid-to-solid ratio) in a sample of pulp. This figure is valuable in two waysdirectly, because for each unit process and operation in milling the optimum pulp density must be established and maintained, and indirectly, because certain important tonnage calculations are based on pulp density.

As used in these formulas the specific gravity of the ore is obtained simply by weighing a liter of mill pulp, then drying and weighing the ore. With these two weights formula (2) may be used to obtain K, and then formula (1) to convert to S, the specific gravity. A volumetric flask of one liter capacity provides the necessary accuracy. In laboratory work the ore should be ground wet to make a suitable pulp. This method does not give the true specific gravity of the ore, but an apparent specific gravity which is more suitable for the intended purposes.

A mechanical classifier often receives its feed from a ball mill and produces (1) finished material which overflows to the next operation and (2) sand which returns to the mill for further size-reduction. The term circulating load is defined as the tonnage of sand that returns to the ball mill, and the circulating load ratio is the ratio of circulating load to the tonnage of original feed to the ball mill. Since the feedto the classifier, the overflow of the classifier, and the sand usually are associated with different proportions of water to solid, the calculation of circulating load ratio can be based on a pulp density formula.

Example: A mill in closed circuit with a classifier receives 300 dry tons of crude ore per day, and the percentages of solid are respectively 25, 50, and 84% in the classifier overflow, feed to classifier, and sand, equivalent to L: S ratios of 3.0, 1.0, and 0.190. Then the circulating load ratio equals

A more accurate basis for calculation of tonnage in a grinding circuit is the screen analysis. Samples of the mill discharge, return sand, and the classifier overflow are screen sized, and the cumulative percentages are calculated on several meshes. Let:

The efficiency of a classifier, also determined by means of screen analyses, has been defined as the ratio, expressed as percentage, of the weight of classified material in the overflow to the weight of classifiable material in the feed. Overflow having the same sizing test as the feed is not considered classified material. Let:

When no other method is available an approximation of the tonnage in a pulp stream or in a batch of pulp can be quickly obtained by one of these methods. In the dilution method water is added to astream of pulp at a known rate, or to a batch of pulp in known quantity, and the specific gravity of the pulp ascertained before and after dilution.

In both cases Dx and D2 are dilutions (tons of water per ton of ore) before and after addition of water. These are found from the specific gravities of the pulp, by formulas (4) and (6) or directly by the use of the tabulation on these of Pulp Density Tables.

The Pulp Density Tables were compiled to eliminate the many complicated calculations which were required when using other pulp density tables. The total tank volume required for each twenty-four hour period of treatment is obtained in one computation. The table gives a figure, in cubic feet, which includes the volume of a ton of solids plus the necessary volume of water to make a pulp of the particular specific gravity desired. Multiply this figure by the number of dry tons of feed per twenty-four hours. Then simply adjust this figure to the required treatment time, such as 16, 30, 36, 72 hours.

In the chemical method a strong solution of known concentration of common salt, zinc sulphate, or other easily measured chemical is added to the flowing pulp at a known rate, or to a batch of pulp in known quantity. The degree of dilution of this standard solution by pulp water is ascertained by chemical analysis of solution from a filtered sample, and the tonnage of ore is then calculated from the percentage solid. This method is impractical for most purposes, but occasionally an exceptional circumstance makes its employment advantageous. It has also been suggested as a rapid and accurate method of determining concentrate moistures, but in this application the expense is prohibitive, since ordinary chemicals of reasonable cost are found to react quickly with the concentrate itself.

With the above chart the per cent solids or specific gravity of a pulp can be determined for ores where gravities do not coincide with those in the Pulp Density Tables.This chart can also be used for determining the specific gravity of solids, specific gravity of pulps, orthe per cent solids in pulp if any two of the three are known.

These are used to compute the production of concentrate in a mill or in a particular circuit. The formulas are based on assays of samples, and the results of the calculations are generally accurate as accurate as the sampling, assaying, and crude ore (or other) tonnage on which they depend.

The simplest case is that in which two products only, viz., concentrate and tailing, are made from a given feed. If F, C, and T are tonnages of feed r on-centrate, and tailing respectively; f, c, and t are the assays of the important metal; K, the ratio of concentration (tons of feed to make one ton of concentrate); and R, the recovery of the assayed metal; then

When a feed containing, say, metal 1 and metal z, is divided into three products, e.g., a concentrate rich in metal 1, another concentrate rich in metal z, and a tailing reasonably low in both l and z, several formulas in terms of assays of these two metals and tonnage of feed can be used to obtain the ratio of concentration, the weights of the three products, and the recoveries of 1 and z in their concentrates. For simplification in the following notation, we shall consider a lead-zinc ore from whicha lead concentrate and a zinc concentrate are produced:

The advantages of using the three-product formulas (20-25) instead of the two-product formulas (14-19), are four-fold(a) simplicity, (b) fewer samples involved, (c) intermediate tailing does not have to be kept free of circulating material, (d) greater accuracy if application is fully understood.

In further regard to (d) the three-product formulas have certain limitations. Of the three products involved, two must be concentrates of different metals. Consider the following examples (same as foregoing, with silver assays added):

In this example the formula will give reliable results when lead and zinc assays or silver and zinc assays, but not if silver and lead assays, are used, the reason being that there is no concentration of lead or silver in the second concentrate. Nor is the formula dependable in a milling operation, for example, which yields only a table lead concentratecontaining silver, lead, and zinc, and a flotation concentrate only slightly different in grade, for in this case there is no metal which has been rejected in one product and concentrated in a second. This is not to suggest that the formulas will not give reliable results in such cases, but that the results are not dependablein certain cases one or more tonnages may come out with negative sign, or a recovery may exceed 100%.

To estimate the number of cells required for a flotation operation in which: WTons of solids per 24 hours. RRatio by weight: solution/solids. LSpecific gravity, solution. SSpecific gravity, solids. NNumber of cells required. TContact time in minutes. CVolume of each cell in cu. ft.

Original feed may be applied at the ball mill or the classifier. TTons of original feed. XCirculation factor. A% of minus designated size in feed. B% of minus designated size in overflow. C% of minus designated size in sands. Circulating load = XT. Where X = B-A/A-C Classifier efficiency: 100 x B (A-C)/A (B-C)

Original feed may be applied at theball mill or the primary classifier. TTons of original feed. XPrimary circulation factor. YSecondary circulation factor. A% of minus designated size in feed. B% of minus designated size in primary overflow. C% of minus designated size in primary sands. D% of minus designated size in secondary overflow. E% of minus designated size in secondary sands. Primary Circulating Load = XT. Where X = (B-A) (D-E)/(A-C) (B-E) Primary Classifier Efficiency: 100 xB (A C)/A (B C) Secondary Circulating Load = YT. Where Y = (D-B)/(B-E) Secondary Classifier Efficiency: 100 xD (B-E)/B (D E) Total Circulating Load (X + Y) T.

Lbs. per ton = ml per min x sp gr liquid x % strength/31.7 x tons per 24 hrs.(26) Solid reagents: Lbs. per ton = g per min/31.7 x tons per 24 hrs.(27) Example: 400 ton daily rate, 200 ml per min of 5% xanthate solution Lbs. per ton = 200 x 1 x 5/31.7 x 400 = .079

Generally speaking, the purpose of ore concentration is to increase the value of an ore by recovering most of its valuable contents in one or more concentrated products. The simplest case may be represented by a low grade copper ore which in its natural state could not be economically shipped or smelted. The treatment of such an ore by flotation or some other process of concentration has this purpose: to concentrate the copper into as small a bulk as possible without losing too much of the copper in doing so. Thus there are two important factors. (1) the degree of concentration and (2) the recovery ofcopper.

The question arises: Which of these results is the most desirable, disregarding for the moment the difference in cost of obtaining them? With only the information given above the problem is indeterminate. A number of factors must first be taken into consideration, a few of them being the facilities and cost of transportation and smelting, the price of copper, the grade of the crude ore, and the nature of the contract between seller and buyer of the concentrate.

The problem of comparing test data is further complicated when the ore in question contains more than one valuable metal, and further still when a separation is also made (production of two or more concentrates entirely different in nature). An example of the last is a lead-copper-zinc ore containing also gold and silver, from which are to be produced. (1) a lead concentrate, (2) a copper concentrate, and (3) a zinc concentrate. It can be readily appreciated that an accurate comparison of several tests on an ore of this nature would involve a large number of factors, and thatmathematical formulas to solve such problems would be unwieldy and useless if they included all of these factors.

The value of the products actually made in the laboratory test or in the mill is calculated simply by liquidating the concentrates according to the smelter schedules which apply, using current metal prices, deduction, freight expense, etc., and reducing these figures to value per ton of crude ore by means of the ratios of concentration.

The value of the ore by perfect concentration iscalculated by setting up perfect concentrates, liquidating these according to the same smelter schedulesand with the same metal prices, and reducing theresults to the value per ton of crude ore. A simple example follows:

The value per ton of crude ore is then $10 for lead concentrate and $8.50 for zinc, or a total of $18.50 per ton of crude ore. By perfect concentration, assuming the lead to be as galena and the zinc as sphalerite:

The perfect grade of concentrate is one which contains 100% desired mineral. By referring to the tables Minerals and Their Characteristics (pages 332-339) it is seen that the perfect grade of a copper concentrate will be 63.3% when the copper is in the form of bornite, 79.8% when in the mineral chalcocite, and 34.6% when in the mineral chalcopyrite.

A common association is that of chalcopyrite and galena. In concentrating an ore containing these minerals it is usually desirable to recover the lead and the copper in one concentrate, the perfect grade of which would be 100% galena plus chalcopyrite. If L is the lead assay of the crude ore, and C the copper assay, it is easily shown that the ratio of concentration of perfect concentration is:

% Pb in perfect concentrate = K perfect x L.(30) % Cu in perfect concentrate = K perfect x C..(31) or, directly by the following formula: % Pb in perfect concentrate = 86.58R/R + 2.5.(32) where R represents the ratio:% Pb in crude ore/% Cu in crude ore Formula (32) is very convenient for milling calculations on ores of this type.

by (29) K perfect = 100/5.775+2.887 = 11.545 and % Pb in perfect concentrate = 11.545 x 5 = 57.7% and % Cu in perfect concentrate = 11.545 x 1 = 11.54% or, directly by (32), % Pb = 86.58 x 5/5 + 2.5 = 57.7%

Occasionally the calculation of the grade of perfect concentrate is unnecessary because the smelter may prefer a certain maximum grade. For example, a perfect copper concentrate for an ore containing copper only as chalcocite would run 79.8% copper, but if the smelter is best equipped to handle a 36% copper concentrate, then for milling purposes 36% copper may be considered the perfect grade.

Similarly, in a zinc ore containing marmatite, in which it is known that the maximum possible grade of zinc concentrate is 54% zinc, there would be no point in calculating economic recovery on the basis of a 67% zinc concentrate (pure sphalerite). For example, the following assays of two zinc concentrates show the first to be predominantly sphalerite, the second marmatite:

The sulphur assays show that in the first case all of the iron is present as pyrite, and consequently the zinc mineral is an exceptionally pure sphalerite. This concentrate is therefore very low grade, from the milling point of view, running only 77.6% of perfect grade.On the other hand, the low sulphur assay of concentrate B shows this to be a marmatite, for 10% iron occurs in the form of FeS and only 2.5% iron as pyrite. The zinc mineral in this case contains 55.8% zinc, 10.7% iron, and 33.5% sulphur, and clearly is an intermediate marmatite. From the milling point of view cencentrate B is high grade, running 93% of perfect grade, equivalent to a 62% zinc concentrate on a pure sphalerite.

equipment | classifieds | icmj prospecting & mining journal

equipment | classifieds | icmj prospecting & mining journal

New and used gold mining equipment, including shaker tables, washplants, mills, crushers, motors, dredges, drills, concentrators, drywashers, flotation cells, pumps, jigs, furnaces, ore bins, conveyors, detectors, screens, sluices, highbankers, trommels, gold pans, augers, hoppers, cranes, amalgamators, and more

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ball mill - retsch - powerful grinding and homogenization

ball mill - retsch - powerful grinding and homogenization

Ball mills are among the most variable and effective tools when it comes to size reduction of hard, brittle or fibrous materials. The variety of grinding modes, usable volumes and available grinding tool materials make ball mills the perfect match for a vast range of applications.

RETSCH is the world leading manufacturer of laboratory ball mills and offers the perfect product for each application. The High Energy Ball Mill Emax and MM 500 were developed for grinding with the highest energy input. The innovative design of both, the mills and the grinding jars, allows for continuous grinding down to the nano range in the shortest amount of time - with only minor warming effects. These ball mills are also suitable for mechano chemistry. Mixer Mills grind and homogenize small sample volumes quickly and efficiently by impact and friction. These ball mills are suitable for dry, wet and cryogenic grinding as well as for cell disruption for DNA/RNA recovery. Planetary Ball Mills meet and exceed all requirements for fast and reproducible grinding to analytical fineness. They are used for the most demanding tasks in the laboratory, from routine sample processing to colloidal grinding and advanced materials development. The drum mill is a type of ball mill suitable for the fine grinding of large feed sizes and large sample volumes.

disc mills from retsch - fast and powerful grinding

disc mills from retsch - fast and powerful grinding

RETSCH Vibratory Disc Mills are particularly suitable for rapid, loss-free grinding of hard, brittle and fibrous materials to analytical fineness. The mills are primarily used for sample preparation for spectral analysis. Due to their robust construction disc mills are used under rough conditions in laboratories and pilot plants, as well as online for the quality control of raw materials.

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